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13th International Conference on Advanced Materials and Nanotechnology

Osaka, Japan

MyungDong Kim

MyungDong Kim

Yeungnam University, Republic of Korea

Title: Effects of Brazing Temperature on the Joining Properties of Gdc-Lsm/Metal Joint for Oxygen Transport Membranes

Biography

Biography: MyungDong Kim

Abstract

Reacive air brazing (RAB) is a relatively simple and inexpensive technique to hermetically seal the ceramic/ceramic and ceramic/metal joints. The joints formed by RAB generally reveal an excellent thermal cycling performance and long term stability in high temperature oxidation as well as reduced atmospheres, which can be used for the joining of oxygen transport membranes, solid oxide fuel cells, and solid state sensors, etc. Here, we used RAB technique to produce sound joints between commercially available GDC-LSM ceramics to various metallic alloys, such as AISI 310S, FeCralloy, and Crofer 22 APU. As a prerequisite, utilization of RAB rests on developing a suitable filler material so as to have reasonable wetting for both ceramic and metallic substrates. A widely used filler system based on Ag-10 wt. % CuO was used by forming a green tape through tape casting. The effects of brazing temperatures on the interfacial microstructure and mechanical properties of the GDC-LSM/metal joints were examined. Brazing was performed at different temperatures of 1000, 1050, and 1100°C for 30 min in air. The measurement of wetting angle was performed at each joining temperature to assess the degree of bonding. Interfacial microstructure and formation of various phases, cracks, voids were analyzed using SEM and EDS. Shear strength at room temperature was measured and correlated with the interfacial microstructure, mode of failure and joint thickness.